Antimony(III) oxide, CP. \[\ce{Sb^{3+}(aq) + 3OH^{-}­(aq) <=> Sb(OH)3(s)}\], \[\ce{Sb(OH)3(s) + OH­^{-}­(aq) <=> Sb(OH)4­^{-}­(aq)}\], \[\ce{Sb(OH)3(s) + 3H^{+}(aq) <=> Sb^{3+}(aq) + 3H2O(l) }\]. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries Abstract Antimony holds a high‐specific capacity as a promising anode material for Na‐ion batteries (SIBs) and much research is focused on solving the poor cycling stability issue associated with its large volume expansion during alloying/dealloying processes. 3 Chemical and Physical Properties Expand this section. Antimon(III)-fluorid ist für den Menschen giftig. Jahrhundert ging der Name Antimon als Bezeichnung auf das Metall über. Contents. For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. Choose from 21 different sets of term:sb = antimony (iii) ion flashcards on Quizlet. Außerdem dient es als Beizmittel zum Färben und wird bei der Herstellung von Keramik verwendet. Some specialty pigments contain antimony. Antimony, Sb 3+ Most common oxidation states: +3, +5 M.P. and are physiologically tolerated more than trivalent antimony (antimony(III)) compounds (Winship, 1987). School of Mineral Processing and Bio‐engineering, … Im Periodensystem steht es in der 5. Not very active, but reacts with oxygen, sulfur and chlorine at high temperatures. The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Die von Jöns Jakob Berzelius benutzte Abkürzung Sb wird noch heute als Elementsymbol genutzt. 4 Spectral Information Expand this section. Choose from 97 different sets of term:sb 3 = antimony (iii) ion flashcards on Quizlet. Antimony(III) oxide is a useful catalyst in the production of polyethylene terephthalate (PET plastic) and the vulcanization of rubber. Antimony(III) oxide has suspected carcinogenic potential for humans. ANTIMONY CATION (3+) More... +)) Validated by Experts, Validated by Users, Non-Validated, Removed by Users. 15. Search for more papers by this author. Component Compounds: CID 5354495 (Antimony) CID 783 (Hydrogen) Dates: Modify . Chemical Formula: Sb+ 3. click here for details. The electron configuration for antimony is 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 3. Abstract Antimony, a pollutant of priority interest by United States Environment Protection Agency (USEPA) and Europe Union (EU), is detected in soil and water with elevated concentration due to its extensive use in a variety of industries. Antimon(III)-oxid (auch Antimontrioxid genannt) ist eine Antimonverbindung mit der Summenformel Sb2O3. Antimony (3+) Please visit the Antimony element page for information specific to the chemical element of the periodic table. Structural Diversity in Cesium Bismuth Halide Nanocrystals. 2 Names and Identifiers Expand this … The toxicity of antimony(III) ion is 10 times higher than that of antimony(V) ion, and antimony(III) has been shown to cause lung cancer (Garbooe et al., 1997). ID of ANTIMONY Cations by Precipitation Reactions : RELEASE DATE: 16 JULY 1997 : LAST UPDATE: 31-July-98 : VERSION HISTORY: 1.0, 1.1, 1.2 ( Context updates) V2.0 ( Text and formatting update - Sep-2009) INTRODUCTION: This is an account on how to detect Antimony ions in solution by simple precipitation reactions. Antimon wurde in Form seiner Verbindungen schon in der Bronzezeit als Zuschlag zu Kupfer verwendet, um Bronze herzustellen (Funde von Velem-St. Vid in Ungarn) und auch im Altertum genutzt. State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083 China . CHEBI:30302 [DBID] UNII:069647RPT5 [DBID] UNII-069647RPT5 [DBID] Predicted - ACD/Labs; Predicted - EPISuite; Predicted - ChemAxon; Predicted data is generated using the ACD/Labs … InChI=1S/Sb/q+3 Tianjing Wu. Antimony has been extensively used in lead alloys, battery grids, bearing metal, cable sheathing, plumber’s solder, pewter, ammunition, sheet, and pipe. Ganz siche… CopyCopied, CSID:94667, http://www.chemspider.com/Chemical-Structure.94667.html (accessed 13:28, Jan 6, 2021) Sicherheitshinweise. Have questions or comments? Heavy metal ions such as Sb(III) are toxic and carcinogenic at relatively low concentrations. Chenyang Zhang. The noble gas electron configuration is: The... See full answer below. Construction of 2D Antimony(III) Selenide Nanosheets for Highly Efficient Photonic Cancer Theranostics. Canadian Metallurgical Quarterly: Vol. Download. Tweet. Stibnit)) ist ein chemisches Element mit dem Elementsymbol Sb (von lateinisch Stibium (Grau-)Spießglanz) und der Ordnungszahl 51. Under moderately acidic conditions, \(\ce{H2S}\) precipitates red \(\ce{Sb2S3}\). Unless otherwise noted, LibreTexts content is licensed by CC BY-NC-SA 3.0. 1380 o. Density 6.69 g/cm 3. Among several industrial applications of antimony compounds, antimony trioxide is largely employed in the production of glassware and ceramics. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries. 47, No. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. pricing. 1 Structures Expand this section. Resources Search for: ANTIMONY (III) ION . WEB … This article is cited by 83 publications. Antimony (V) ion - chemical information, properties, structures, articles, patents and more chemical data. 2020-11-29. Antimon [antiˈmoːn] (von lateinisch Antimonium, vermutlich von arabisch al-ithmîd(un) (ithmid / إثمد / iṯmid, Antimonsulfid bzw. Safety. Hauptgruppe, bzw. State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083 China. 10783 ≥95.0% ; Sigma-Aldrich pricing. (2008). Search for more papers by this author . Antimony(III) Cite. Department of Ultrasound, Sir Run Run Shaw Hospital, Zhejiang University School of Medicine, Hangzhou 310016, P. R. China. Halides of ns2 metal ions have recently regained broad research interest as bright narrowband and broadband emitters. Missed the LibreFest? 630 o. B.P. Main group metal ions antimony (III) and bismuth (III) with external electron shell of s 2 configuration belong to the so-called mercury-like ions. However, antimony purification from liquid system is yet poorly documented. Create . Email. Learn term:sb 3 = antimony (iii) ion with free interactive flashcards. Die koptische Bezeichnung für das Schminkpuder Antimonsulfid ging über das Griechische in das Lateinische stibium über. Antimony trisulfide (Sb 2 S 3) is found in nature as the crystalline mineral stibnite and the amorphous red mineral metastibnite. Characteristic Reactions of Antimony Ions (Sb³⁺) Last updated; Save as PDF Page ID 97261; Contributed by James P. Birk; Professor Emeritus (Chemistry) at Arizona State University; Chloride Ion: Aqueous Ammonia: Sodium Hydroxide; Hydrogen Sulfide; Water; Reducing Agents; No Reaction; Most common oxidation states: +3, +5; M.P. Share. ≥99.95% trace metals basis. Yadan Zhou. 337374. Watch the recordings here on Youtube! Molecular Weight: 531.71. More... Molecular Weight: 291.52 g/mol. Antimony Black. The types of ionic mobility in these compounds were identified at 150–470 K. The sulphuric acid reaction produces SO 2. Antimony does not react with hydrochloric acid in the absence of oxygen. More by Yadan Zhou, Wei Feng* Wei Feng . antimony(iii) 23713-48-6 [RN] Antimony [Wiki] ANTIMONY (III) ION. ANTIMONY IN DRINKING-WATER 2 1.5 Environmental fate The emission of antimony into the human environment … 630º; B.P. 2 Names and Identifiers Expand this section. 2020-12-26. Solutions of antimony(III) chloride in \(\ce{HCl}\) react when added to excess water to form the basic, white, insoluble salt \(\ce{SbOCl}\). Linear Formula: SbCl3. Sodium hydroxide also precipitates \(\ce{Sb(OH)3}\), which is amphoteric and dissolves in an excess of hydroxide and in acids. 2005-03-27. Sb(III) reacts with aqueous ammonia to precipitate white \(\ce{Sb(OH)3}\). 19F and 1Н NMR methods were used to study ion mobility in M6Sb4(SO4)3F12 (M = Rb, Cs, NH4) and (NH4)2Sb(SO4)F3 complex antimony(III) sulfate fluorides with alkali cations and ammonium. Chloride Ion: Materials that exhibit large and rapid switching of their optical properties in the visible spectrum hold the key to color-changing devices. Periode und der 5. 6 Chemical Vendors. In the presence of \(\ce{HCl}\), either aluminum or iron will reduce \(\ce{Sb^{3+}}\) to \(\ce{Sb}\) metal, which will be deposited as black particles. Dates: Modify . PubChem CID: 102060556: Structure: Find Similar Structures. No reaction observable, but will be present as \(\ce{SbCl4­}\). Sb(III) is particularly appealing for its oxidative stability (compared to Ge2+ and Sn2+) and low toxicity (compared to Pb2+). A study of the ion exchange removal of antimony(III) and antimony(V) from copper electrolytes. Sigma-Aldrich. IUPAC-Gruppe oder Stickstoffgruppe. The known anti- mony(III) based ion exchangers are antimony(llI) arsenate, antimony(III) molybdate", antimony(llI) selenite and antimony(III) tungstate", But a hetero- polyacid ion exchanger based on annmonytlll) has not yet been reported. \[\ce{Sb2S3(s) + 3S2^{-}­(aq) <=> 2SbS33­(aq)}\], \[\ce{Sb2S3(s) + 6H^{+}(aq) + 8Cl­^{-}(aq) <=> 2SbCl4^{2-}­(aq) + 3H2S(aq)}\]. A STUDY OF THE ION EXCHANGE REMOVAL OF ANTIMONY(III) AND ANTIMONY(V) FROM COPPER ELECTROLYTES. Antimon(III)-fluorid wird als mäßig aktives Fluorierungsmittel, bevorzugt für niedrig schmelzende Fluoride, verwendet. APT (tartar emetic) has been used to induce vomiting in poisoning cases, and antimony compounds such as piperazine antimony tartrate were used as drugs against bilharzia. Characteristic Reactions of Antimony Ions (Sb³⁺), [ "article:topic", "authorname:jbirk", "Antimony", "showtoc:no" ], https://chem.libretexts.org/@app/auth/2/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FBookshelves%2FAnalytical_Chemistry%2FSupplemental_Modules_(Analytical_Chemistry)%2FQualitative_Analysis%2FCharacteristic_Reactions_of_Select_Metal_Ions%2FAntimony%252C_Sb3, Characteristic Reactions of Select Metal Ions, Characteristic Reactions of Aluminum Ions (Al³⁺), information contact us at info@libretexts.org, status page at https://status.libretexts.org, Characteristic reactions of \(\ce{Sb^{3+}}\): (Sb(III) is the more stable oxidation state. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. Antimony is dissolved in hot concentrated sulphuric acid, H 2 SO 4, or nitric acid, HNO 3, forming Sb(III) solutions. Antimony(III) Sulfide Thin Films as a Photoanode Material in Photocatalytic Water Splitting | ACS Applied Materials & Interfaces For the first time, we present exploratory investigations on the performance of thermally evaporated Sb2S3 thin film photoanodes for solar-assisted water-splitting applications. 2015-12-24. Learn term:sb = antimony (iii) ion with free interactive flashcards. Legal. Create . Contents. Molecular Formula: H 2 Sb: Synonyms: Antimony(III) Molecular Weight: 123.78 g/mol. CopyCopied, FAWGZAFXDJGWBB-UHFFFAOYSA-N Diese lassen sich anschließend vom überschüssigen Antimon(III)-fluorid abdestillieren. SDS; Antimony(III) sulfide. IUPAC Name: antimony(3+) CAS Number: 23713-48-6 . CAS Number: 10025-91-9. Im 17. ). More... Antimony (3+) is a monoatomic trication and an elemental antimony. Antimony(III) oxide is an opacifying agent for glasses, ceramics and enamels. 1 Structures Expand this section. In der stabilen Modifikation ist es ein silberglänzendes und sprödes Halbmetall. 307-316. It also is used in the production of ruby-colored glass and in plastics as a flame retardant. Tianjing Wu. 1 Product Result | Match Criteria: Product Name, Property, Description Linear Formula: Sb 2 (SO 4) 3. Es gehört zur Stoffklasse der Oxide. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite™, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite™, Compounds with the same molecular formula, Search Google for structures with same skeleton. Antimony trisulfide (Sb2S3) is a chalcogenide material that exhibits large refractive index changes of ~1 between crystalline and amorphous states. Antimony Trioxide Nanopowder. Antimony(III) sulfate. 5 Related Records Expand this section. Characteristics: Brittle, silvery. 3, pp. Synonym: Antimony trichloride. Sidney E. Creutz, Hongbin Liu, Mitchell E. Kaiser, Xiaosong Li, Daniel R. Gamelin. Molecular Weight: 228.12. Recently, luminescent antimony (III) and bismuth (III) hybrid halide compounds have aroused great research interest. CAS Number: 7446-32-4. Yadan Zhou. Characteristic reactions of Sb 3+: (Sb(III) is the more stable oxidation state.) This sulfide is soluble in solutions of hot \(\ce{NaOH}\) which contain excess sulfide ion and in hot, concentrated (12 M) \(\ce{HCl}\). School of Mineral Processing and Bio‐engineering, … Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries. Chenyang Zhang. 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